Bosses


Giovanni (Former, depends)
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Boss of Team Rocket, known for his calm steely determination to get what he wants, focused on gathering a Pokémon army to take over the world. He is generally well feared and respected by his subordinates.
He served a role as both the Boss and a secret ground type gym leader in Viridian City, he later disbands Team Rocket in the games, this is not mentioned in the anime. He also has a son, Silver.

Madame Boss (Former + deceased)
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Boss and founder of Team Rocket, known in her prime as a fierce and adept leader, she was largely motivated by money and profits only. She did not care for Pokémon and never had any, she saw them as powerful tools for her world domination.
Her relationship with her son, Giovanni, was strained and hostile, but Giovanni eventually took her place as Boss.

Admins


Proton
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Petrel
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Ariana
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Archer
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Sham
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Carl
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Grey
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Scientists

Gideon
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Fuji
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Zager
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Namba
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Sebastian

Agents

(Not including former agents other than Butch, Cassidy, Christopher and Sird!)


Carr
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Orm
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Sird (Former)
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Member of the Three Beasts

Viper
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Works as the Drill Sergeant for the Team Rocket academy, he is in charge of new recruits in training.

Wendy
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Works for Team Rocket Human Resources, and she has direct access to Giovanni. Has a grudge against Jessie for an overdue debt from their training days. In which the two had smoothies together, Wendy paid, Jessie said she would repay her someday, and she didn't. The grudge lasted ever since.

Matori
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Mtori is the secretary and elite officer for Boss Giovanni, she acts as his voice at times, providing mission details and recieving reports on his behalf. She is very serious about her job, and is very faithful to Giovanni. She leads a sect of agents known as the Matori Matrix.

Rocket scout
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Iron Masked Marauder
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Ken
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Sub leader for high ranking agent, Lt. Surge. Al
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Harry
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Tyson
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Miyamoto (Former + deceased ?)
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Koga
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Lt. Surge
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Sabrina
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Domino
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Also known as "009", and "Black Tulip", she is an elite officer, she has direct contact with Giovanni, Domino takes orders from him directly, and she is seemingly closer to him than most. She is known for having a bubbly and friendly persona, before dropping the face and revealing her cruel, ruthless self.

Annie (Dub only)
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Seemingly a reputable agent in the English dub of Pokémon, she works with her younger sister Oakley. Annie is suave, well versed in tech, determined and vain, much like her sister. She is not as serious about her work, however, as she is more concerned with herself. She works to capture Latios and Latias

Oakley (Dub only)
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Seemingly a reputable agent in the English dub of Pokémon, she works with her older sister Annie. She is manipulative, power hungry, and intellegent, acting as the leader and mastermind of sorts. She works to capture Latios and Latias

Attila
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A confidently high ranking member, laid back and assured in his work, he often speaks informally and has a tedancy to mess with his targets. Attila had a history with Pokémon poaching before he joined Team Rocket. His rough nature sharply contradicts Hun's own.

Hun
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Calm, stoic and self assured, he acts as a balance to Attila's violence, and keeps him in line. He is ever so slighly vindictive, and he believes ardently that Pokémon exist for the needs of humanity and Team Rocket by extension, despite understanding their intellegence.

Butch (Former)
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Cassidy (Former)
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Jessie
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Apart of the anime TR trio , she is very passionate, vain, and headstrong. She comes from an extremely poor background, joining Team Rocket later in life after multiple endeavors for success. Her passion shows especially in her motivation for evil, James and Meowth along with her.

James
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Apart of the anime TR trio, he is kind natured, slightly conceited and dramatic. He was raised into a hugely wealthy, controlling family and was pressed into an arranged marriage as a child before he ran away from home. He joined Team Rocket for a chance at freedom. Has a lifelong appreciation for Pokémon.

Meowth
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Apart of the anime TR trio,

Pierce
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Pierce is a serious and hardworking agent, he acts as a messenger of sorts for Jessie James and Meowth when they cannot contact the Boss. He provides help and escape to the trio throughout the Black and White anime.

Mondo
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Mondo is a trusting and loyal agent who works behind the scenes for Jessie James and Meowth, providing them with supplies and support, he respects the trio greatly and looks up to them as his mentors in some way.

Jubei
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Jessie's 12th Team Rocket training partner, the two failed at a practice heist and Jubei got a poor grade for it.

Kaede
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Childhood friends with gym leader Erica, she is viciously allergic to pollen and grass type Pokémon, is often shown tired and sniffly due to her constant approximation to grass types and things of the sort.

Christopher (Former)
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Ex Team Rocket member turned Ramen shop founder, he's a bright eyed, positive person with a passion for his job. He runs a chain of noodle shops named after Jessie and James. He knew them during Rocket training, and a few small acts such as the trio taking him to ramen when he was down, inspired him to chase his dream of opening a ramen shop. Similar to Mondo, he looks up to the three of them as mentors.